Apparently various old music is available on I-Tunes, unfortunately it appears to take some looking for to find.
http://www.boingboing.net/2008/11/12/great-old-disney-mus.html
Classic Disney Music on ITunes
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Thu, 11/13/2008 - 17:52
Classic Disney Music on ITunes
Fri, 11/14/2008 - 14:22
That's one of the great things about ITunes, more and more stuff will eventually make it's way there since it costs nothing to store. You'll be able to find almost any rarity. They just need to come up with the best ways to organize it.
Fri, 03/06/2009 - 21:29
Just read this!!
How exactly do I get to the music?
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May 2008 CSR 
Wed, 03/18/2009 - 14:09
I think you just have to search for the albums on Itunes.